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Calculate Ph for Oh 1.0 10-5 M

Reviewed by Calculator Editorial Team

The pH of a solution can be calculated from its hydroxide (OH⁻) concentration using the pH = 14 - pOH formula. This calculator provides an easy way to determine the pH when you know the OH⁻ concentration in moles per liter (M).

How to Calculate pH from OH⁻ Concentration

To calculate the pH of a solution when you know the hydroxide concentration (OH⁻), follow these steps:

  1. Determine the hydroxide concentration in moles per liter (M).
  2. Calculate the pOH using the formula: pOH = -log₁₀[OH⁻].
  3. Use the relationship between pH and pOH: pH = 14 - pOH.

This method works for aqueous solutions at standard temperature (25°C) where water autoionization is assumed to be 1.0 × 10⁻¹⁴ M.

Key Formula

pH = 14 - pOH

pOH = -log₁₀[OH⁻]

The pH Calculation Formula

The pH of a solution is defined as the negative logarithm (base 10) of the hydrogen ion concentration:

pH = -log₁₀[H⁺]

For aqueous solutions, the product of hydrogen ion and hydroxide ion concentrations is constant:

[H⁺][OH⁻] = 1.0 × 10⁻¹⁴ M² (at 25°C)

Taking the negative logarithm of both sides gives the relationship between pH and pOH:

pH + pOH = 14

Therefore, pH = 14 - pOH

Example Calculation

Let's calculate the pH for a solution with an OH⁻ concentration of 1.0 × 10⁻⁵ M:

  1. Given: [OH⁻] = 1.0 × 10⁻⁵ M
  2. Calculate pOH: pOH = -log₁₀(1.0 × 10⁻⁵) = 5
  3. Calculate pH: pH = 14 - pOH = 14 - 5 = 9

The pH of this solution is 9.

Important Note

This calculation assumes standard temperature (25°C) and that the solution is sufficiently dilute that activity coefficients can be approximated as 1.

Interpreting the pH Result

A pH of 9 indicates that the solution is basic. Here's what this means:

  • The hydrogen ion concentration is 1.0 × 10⁻⁵ M
  • The hydroxide ion concentration is 1.0 × 10⁻⁵ M
  • The solution is 100,000 times more basic than neutral (pH 7)

Solutions with pH values between 7 and 14 are considered basic, with higher pH values indicating stronger bases.

Frequently Asked Questions

What is the relationship between pH and pOH?
The sum of pH and pOH is always 14 for aqueous solutions at standard temperature (25°C). This is derived from the water autoionization constant.
Can I use this formula for any temperature?
No, this formula assumes standard temperature (25°C). At different temperatures, the water autoionization constant changes, and a temperature correction factor would be needed.
What if my solution is very concentrated?
For concentrated solutions, activity coefficients become important and should be considered. This calculator assumes dilute solutions where activity coefficients are approximately 1.
How accurate is this calculation?
This calculator provides accurate results for dilute aqueous solutions at standard temperature, with typical laboratory precision.
What does a pH of 9 mean in practical terms?
A pH of 9 means the solution is strongly basic and would feel slippery to the skin, would react with acids, and would have a strong alkaline taste.